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Abstract A primary goal of exoplanet science is to measure the atmospheric composition of gas giants in order to infer their formation and migration histories. Common diagnostics for planet formation are the atmospheric metallicity ([M/H]) and the carbon-to-oxygen (C/O) ratio as measured through transit or emission spectroscopy. The C/O ratio in particular can be used to approximately place a planet’s initial formation radius from the stellar host, but a given C/O ratio may not be unique to formation location. This degeneracy can be broken by combining measurements of both the C/O ratio and the atmospheric refractory-to-volatile ratio. We report the measurement of both quantities for the atmosphere of the canonical ultrahot Jupiter WASP-121 b using the high-resolution (R= 45,000) IGRINS instrument on Gemini South. Probing the planet’s direct thermal emission in both pre- and post-secondary eclipse orbital phases, we infer that WASP-121 b has a significantly superstellar C/O ratio of ${0.70}_{-0.10}^{+0.07}$and a moderately superstellar refractory-to-volatile ratio at ${3.83}_{-1.67}^{+3.62}\times$stellar. This combination is most consistent with formation between the soot line and H₂O snow line, but we cannot rule out formation between the H₂O and CO snow lines or beyond the CO snow line. We also measure velocity offsets between H₂O, CO, and OH, potentially an effect of chemical inhomogeneity on the planet dayside. This study highlights the ability to measure both C/O and refractory-to-volatile ratios via high-resolution spectroscopy in the near-IRHandKbands. 

Abstract Ultra-hot Jupiters (UHJs) are among the best targets for atmospheric characterization at high spectral resolution. Resolving their transmission spectra as a function of orbital phase offers a unique window into the 3D nature of these objects. In this work, we present three transits of the UHJ WASP-121b observed with Gemini-S/IGRINS. For the first time, we measure the phase-dependent absorption signals of CO and H₂O in the atmosphere of an exoplanet, and we find that they are different. While the blueshift of CO increases during the transit, the absorption lines of H₂O become less blueshifted with phase, and even show a redshift in the second half of the transit. These measurements reveal the distinct spatial distributions of both molecules across the atmospheres of UHJs. Also, we find that the H₂O signal is absent in the first quarter of the transit, potentially hinting at cloud formation on the evening terminator of WASP-121b. To further interpret the absorption trails of CO and H₂O, as well as the Doppler shifts of Fe previously measured with VLT/ESPRESSO, we compare the data to simulated transits of WASP-121b. To this end, we post-process the outputs of the global circulation models with a 3D Monte-Carlo radiative transfer code. Our analysis shows that the atmosphere of WASP-121b is subject to atmospheric drag, as previously suggested by small hotspot offsets inferred from phase-curve observations. Our study highlights the importance of phase-resolved spectroscopy in unravelling the complex atmospheric structure of UHJs and sets the stage for further investigations into their chemistry and dynamics. 

Abstract The near-infrared transmission spectrum of the warm sub-Neptune exoplanet GJ 1214 b has been observed to be flat and featureless, implying a high metallicity atmosphere with abundant aerosols. Recent JWST MIRI Low Resolution Spectrometer observations of a phase curve of GJ 1214 b showed that its transmission spectrum is flat out into the mid-infrared. In this paper, we use the combined near- and mid-infrared transmission spectrum of GJ 1214 b to constrain its atmospheric composition and aerosol properties. We generate a grid of photochemical haze models using an aerosol microphysics code for a number of background atmospheres spanning metallicities from 100 to 1000× solar, as well as a steam atmosphere scenario. The flatness of the combined data set largely rules out atmospheric metallicities ≤300× solar due to their large corresponding molecular feature amplitudes, preferring values ≥1000× solar and column haze production rates ≥10 −10 g cm −2 s −1 . The steam atmosphere scenario with similarly high haze production rates also exhibits sufficiently small molecular features to be consistent with the transmission spectrum. These compositions imply that atmospheric mean molecular weights ≥15 g mol −1 are needed to fit the data. Our results suggest that haze production is highly efficient on GJ 1214 b and could involve non-hydrocarbon, non-nitrogen haze precursors. Further characterization of GJ 1214 b’s atmosphere would likely require multiple transits and eclipses using JWST across the near- and mid-infrared, potentially complemented by ground-based high-resolution transmission spectroscopy. 

Abstract Close-in lava planets represent an extreme example of terrestrial worlds, but their high temperatures may allow us to probe a diversity of crustal compositions. The brightest and most well-studied of these objects is 55 Cancri e, a nearby super-Earth with a remarkably short 17 hr orbit. However, despite numerous studies, debate remains about the existence and composition of its atmosphere. We present upper limits on the atmospheric pressure of 55 Cnc e derived from high-resolution time-series spectra taken with Gemini-N/MAROON-X. Our results are consistent with current crustal evaporation models for this planet which predict a thin ∼100 mbar atmosphere. We conclude that, if a mineral atmosphere is present on 55 Cnc e, the atmospheric pressure is below 100 mbar. 

Abstract The recent inference of sulfur dioxide (SO₂) in the atmosphere of the hot (approximately 1,100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations^1–3suggests that photochemistry is a key process in high-temperature exoplanet atmospheres⁴. This is because of the low (<1 ppb) abundance of SO₂under thermochemical equilibrium compared with that produced from the photochemistry of H₂O and H₂S (1–10 ppm)^4–9. However, the SO₂inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 μm and, therefore, the detection of other SO₂absorption bands at different wavelengths is needed to better constrain the SO₂abundance. Here we report the detection of SO₂spectral features at 7.7 and 8.5 μm in the 5–12-μm transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS)¹⁰. Our observations suggest an abundance of SO₂of 0.5–25 ppm (1σrange), consistent with previous findings⁴. As well as SO₂, we find broad water-vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 μm. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy-element content (metallicity) for WASP-39b of approximately 7.1–8.0 times solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range. 

Abstract Close-in giant exoplanets with temperatures greater than 2,000 K (‘ultra-hot Jupiters’) have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble Space Telescope (HST) and Spitzer Space Telescope^1–3. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis^3–12. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS¹³instrument on the JWST. The data span 0.85 to 2.85 μm in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at >6σconfidence) and evidence for optical opacity, possibly attributable to H⁻, TiO and VO (combined significance of 3.8σ). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy-element abundance (‘metallicity’,$${\rm{M/H}}=1.0{3}_{-0.51}^{+1.11}$$ $\mathrm{M/H}=1.03_{-0.51}^{+1.11}$times solar) and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the substellar point that decreases steeply and symmetrically with longitude towards the terminators. 

Abstract Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability¹. However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program^2,3found a spectral absorption feature at 4.05 μm arising from sulfur dioxide (SO₂) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M_J) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref. ⁴). The most plausible way of generating SO₂in such an atmosphere is through photochemical processes^5,6. Here we show that the SO₂distribution computed by a suite of photochemical models robustly explains the 4.05-μm spectral feature identified by JWST transmission observations⁷with NIRSpec PRISM (2.7σ)⁸and G395H (4.5σ)⁹. SO₂is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H₂S) is destroyed. The sensitivity of the SO₂feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO₂also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations. 

Abstract The Saturn-mass exoplanet WASP-39b has been the subject of extensive efforts to determine its atmospheric properties using transmission spectroscopy^1–4. However, these efforts have been hampered by modelling degeneracies between composition and cloud properties that are caused by limited data quality^5–9. Here we present the transmission spectrum of WASP-39b obtained using the Single-Object Slitless Spectroscopy (SOSS) mode of the Near Infrared Imager and Slitless Spectrograph (NIRISS) instrument on the JWST. This spectrum spans 0.6–2.8 μm in wavelength and shows several water-absorption bands, the potassium resonance doublet and signatures of clouds. The precision and broad wavelength coverage of NIRISS/SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favouring a heavy-element enhancement (‘metallicity’) of about 10–30 times the solar value, a sub-solar carbon-to-oxygen (C/O) ratio and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are also best explained by wavelength-dependent, non-grey clouds with inhomogeneous coverageof the planet’s terminator. 

Abstract Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems^1,2. Access to the chemical inventory of an exoplanet requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based^3–5and high-resolution ground-based^6–8facilities. Here we report the medium-resolution (R ≈ 600) transmission spectrum of an exoplanet atmosphere between 3 and 5 μm covering several absorption features for the Saturn-mass exoplanet WASP-39b (ref. ⁹), obtained with the Near Infrared Spectrograph (NIRSpec) G395H grating of JWST. Our observations achieve 1.46 times photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO₂(28.5σ) and H₂O (21.5σ), and identify SO₂as the source of absorption at 4.1 μm (4.8σ). Best-fit atmospheric models range between 3 and 10 times solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO₂, underscore the importance of characterizing the chemistry in exoplanet atmospheres and showcase NIRSpec G395H as an excellent mode for time-series observations over this critical wavelength range¹⁰.